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From the One Wiki to Rule Them All, the Lord of the Rings Encyclopedia.
The Witch-king of Angmar was the chief of the Nazgûl of Middle-earth.
The Witch-king was originally a human king. In the Second Age, he was given one of nine Rings of Power to help rule over his realm. He and eight others were already in the service of Sauron, the Dark Lord of Mordor. The Rings gave them incredible power, which they used to further their own ambitions, but eventually the Rings completely corrupted them and turned them into the ghostly, undead Nazgûl.
The first sighting of the Nazgûl in Middle-earth was reported in 2251 of the Second Age. For the next 1200 years, the Lord of the Nazgûl would serve Sauron as his second in command. He fought in the war against the Last Alliance of Elves and Men between 3434 and 3441 of the Second Age. It was in 3441 that Sauron was defeated by Isildur and the nine Nazgûl disappeared from Middle-Earth.